DEGRADATION DE NITROBENZENE PAR ADSORPTION SUR ARGILE NATURELLE COUPLEE D’UNE OXYDATION PAR LE REACTIF DE FENTON
Résumé
Nitrobenzene is an important chemical which used in the manufacture of many products such as dyes, plastics, pesticides, explosives, pharmaceuticals products, etc. It is very toxic even present as traces in industrial waste liquids effluents. It may constitute a potential pollution source of faun and flare. It is necessary to investigate technical treatment in aim to reduce the residual concentration of nitrobenzene in environment. In this work the removal of nitrobenzene from synthesized aqueous solutions was carried out by adsorption onto natural clay in presence of Fenton’s reagent at batch processes. The equilibrium was reached at the end of 20 minutes. The adsorption isotherm was well described by the Dubinin-Radushkevich model. The high efficiency of treatment by this technical is 66.51 %, was obtained at the optimum conditions: initial concentration of nitrobenzene (C0 = 246 mg/l), dose of natural clay (DNC = 0.6 g/L), concentration of hydrogen peroxide ([H2O2] = 5μmol/L) and concentration of ferrous ion ([Fe2+] = 50μmol/L).Références
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[2] S.B.Haderlein, R.P. Schwarzenbach. Adsorption of substituted nitrobenzene’s and nitrophenols to mineral surfaces. Envron. Sci. Tech. 27 (1993) 316.
[3] E.A.Reynoso-Soto, S.P.Sicairos. Photocatalytic degradation of nitrobenzene using nanocrystalline TiO2 photocatalyst doped with Zn ions. Mex. Chem. Soc. 57(4) (2013) 298-305.
[4] S.A.Boyd, GY.Sheng, BJ.Teppen, C.T.Johnston. Mechanisms for the adsorption of substituted nitrobenzene’s by smectite clays. Environ. Sc. Tech. 35 (2001) 4227.
[5] O.V.Makarova. T.Rajh, M.C. Thurnaue. A. Martin, P.A. Kemme, D.Cropek. Surface modification of TiO2 nanoparticles for photochemical reduction of nitrobenzene. Envron. Sci. Tech. 34 (2000) 4797.
[6] A.Latifoglu, M.D. Gurol. The effect of humic acids on nitrobenzene oxidation by ozonation and O3/UV processes. Water Res. 37 (2003) 1879.
[7] Tekin, Husein, Bilkay. Use of Fenton oxidation to improve the biodegradability of pharmaceutical wastewater. Hazard Mater. 136 (2) (2006) 258-265.
[8] Mass.R, Chaudhari.S. Adsorption and biological discoloration of azo dye reactive red-2 in semi continuous anaerobic reactor. Process Biochemical. 40 (2005) 699-705.
[9] Wang, Xiao-J, Song, Yang. Combined Fenton oxidation and aerobic biological process for the treatment a surfactant wastewater containing abundant sulfate. Hazard Mater. 160 (2008) 344-348.
[10] Fenton.H.J. Oxidation properties of the H2O2/Fe2+ system and its application. Chem. Soc. 65 (1884) 889-899.
[11] Gottschalk.C, Libra.J.A, Saupe.A. Ozonation of water and wastewater. Wiley-VCH (2000).
[12] Kao.PN, Tzeng.JH, Hang.TL. Removal of chlorophenols from aqueous solution by fly ash. Hazard Mater. 76 (2000) 237-249.
[13] Barhoumi.M, Beurroies.I,Denoyel.R, ai.Hanna.K. Co-adsorption of alkylphenols and nonionic surfactants onto kaolinite. Colloids Surf. A 219 (2003) 25-33.
[14] [14] Koh.S, Dixon.JB. Preparation and application of organominerals as adsorbents of phenol, benzene and toluene. Appl. Clay Sci. 18 (2001) 111-122.
[15] Munaf.E, Zein.R, kurniadi.R, kurniadi.I. The use of rice husk for removal of phenol from wastewater as studies using 4-aminoantipyrine spectrophotometric method. Environ. Tech. 18 (3) (1997) 355-358.
[16] Arris.S, Benceikh, M,Miniai.A. Batch adsorption of phenol from industrial wastewater using cereal by products as a new adsorbent. Energy Procedia. 18(2012) 1135-1144.
[17] Elmir.I, Bagane.M. Adsorption of nitrobenzene by natural and activated clay. Courrier du savoir 20 (2015) 31-40.
[18] Jiao.W, Liu.Y, Liu.W, Li.J, Shao.F, Wang.C. Degradation of nitrobenzene-containing wastewater with O3 and H2O2 by High Gravity Technology. China. P. Proc and Petroch. Tech. 15 (1) (2003) 85-94.
[19] Munter.R. Advanced oxidation processes-current status and prospects. Proc. Estonia Acd. Sci. Chem. 50 (2) (2001) 59-80.
[20] Lian.MS, Francis M. Techniques de l’Ingénieur, Traité de Génie des Procédés, 3éme édition, Mc Graw-Hill (2003).
[21] Itodo.A.U, Itodo.H.U. Sorption energy estimation using Dubinin-Radushkevich and Temkin adsorption isotherms. Life science journal 7 (2010) 31-39.
[22] K.P.Singh, D.Mohan, S.Sinha, G.S.Tondon, D.Gosh. Color removal from wastewater using low-cost activated carbon derived from agricultural waste maternal. Ind. Eng. Chem. Res. 42 (2003) 1965.
[23] M.Abdelkreem. Adsorption of phenol from industrial wastewater using olive mill waste. APCBEE Procedia 5 (2013) 349-357.
Publiée
2016-11-29
Comment citer
ELMIR, IMED; BAGUANE, MOHAMED.
DEGRADATION DE NITROBENZENE PAR ADSORPTION SUR ARGILE NATURELLE COUPLEE D’UNE OXYDATION PAR LE REACTIF DE FENTON.
Courrier du Savoir, [S.l.], v. 21, nov. 2016.
ISSN 1112-3338.
Disponible à l'adresse : >https://revues.univ-biskra.dz/index.php/cds/article/view/1830>. Date de consultation : 26 avr. 2024
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